Process design and economics for the conversion of. Tea guided development of processes and catalysts for hydrocarbon fuel production from biooil mypp target. Challenges and opportunities for the synthesis of novel. Considerable effort has been devoted to biooil bo upgrading by either modifying the fast pyrolysis process insitu upgrading to obtain the desired liquid product hydropyrolysis, catalytic flash pyrolysis, etc or by upgrading the bo product by additional treatments postpyrolysis upgrading, e. We will test the hypothesis that nickel ni and ruthenium ru catalytic surfaces can be grown on nanospringsupported mesh structures, which would enhance the catalytic hydrogenation of pyrolysis bio oil to. Also, key assumptions found in the literature for biomass cost, plant capacity, reactor technology, and other variables vary widely among different studies. Comparatively, for hog fuel, the pyrolysis bio oil mass yield was lower at 54% because of inorganics in the biomass, but subsequent upgrading of that bio oil had an average mass yield of 45% to. Small particles desirably and fast heating rates 100 cs to temperatures between 400 and 650 c are common characteristics of fast pyrolysis. Upgrading fast pyrolysis biooil quality by esterification. Two 2000 dry tonne per day scenarios are developed. A box flow diagram for the modeled fast pyrolysis system followed by catalytic bio oil upgrading to gasoline and diesel blendstocks is shown in figure 1.
Battelle is developing small scale 100 tonsday biorefineries using fast pyrolysis bio oil as a platform intermediate product to produce fuels and chemicals. Biooil production of softwood and hardwood forest industry. Tandem catalytic upgrading of biomass fastpyrolysis. Review of methods for upgrading biomassderived fast. Among the main issues are high acidity, instability, and water and oxygen content, which give rise to corrosiveness, polymerization during storage, and a low heating value. A number of studies analyze the technoeconomics of biomass fast pyrolysis to produce bio oil, but very few explore upgrading of bio oil to transportation fuel. Biooils are sustainable fuels obtained from biomass pyrolysis. An overview of fast pyrolysis of biomass sciencedirect. Biomass is transformed into an energy dense and economically transportable intermediate. Bio oil is a promising alternative source of energy produced from fast pyrolysis of biomass. Download hires imagedownload to mspowerpointcite this. Onedimensional biomass fast pyrolysis model with reaction. Bio oils and transportation fuels by fast pyrolysis the. Fast pyrolysis rapid thermal decomposition of organic compounds in the absence of oxygen to produce liquids, char, and gas dry feedstock.
Biooil streams in the current fast pyrolysis catalytic upgrading. Fast pyrolysis and biooil upgrading ascension publishing. Instrument control and data acquisition were done through chromatof software leco. Both routes have been tested using different catalysts. Due to its short residence time, the main products from biomass fast pyrolysis are ethylenerich gases that can be condensed to produce bio oil. Hydrotreatment of fast pyrolysis biooil fractions over. Modularisation of bioenergy systems bioeconomy institute. One of the main aims of the multiyear program plan of the does bioenergy technologies office beto is the production of liquid.
The biooil was mixed with deionized water at the weight ratio of 1. Fast pyrolysis has now achieved a commercial success for production of chemicals and is being actively. Renewable natural gas from biomass gasification via fluidizedbed methanation. Overview of applications of biomass fast pyrolysis oil. Biomass fast pyrolysis is potentially one of the cheapest routes toward renewable liquid fuels.
Flue gas and fast pyrolysis syngas atmospheres are investigated as physical activating agents to further upgrade the biochar into activated carbon. Due to its short residence time, the main products from biomass fast pyrolysis are ethylenerich gases that can be condensed to produce biooil and alcohols rather than char and tar. Considerably greater interest in upgrading biooil sufficiently for it to be used for heat, power and other applications with greater confidence by users. Improving biomass pyrolysis economics by integrating vapor and. Fast pyrolysis bio oil has unfavorable properties that restrict its use in many applications. In the hydrotreatingfcc pathway, two options 14 are available as the hydrogen source for hydrotreating. Biooils were produced through intermediate ip and fast pyrolysis fp. Biorenewables systems analysis bioeconomy institute. Mathematical modeling of fast biomass pyrolysis and biooil. Compatibility of fastpyrolysis biooil with infrastructure. Global challenges global collaborations jim spaeth, chair, iea bioenergy. Estimation of the production cost of fast pyrolysis biooil article pdf available in biomass and bioenergy 36 january 2011 with 9,074 reads how we measure reads. Thermochemical research at nrel enabling the emerging bioeconomy robert m.
Brown and others published fast pyrolysis and biooil upgrading. Opening remarks and presentation of don klass award to douglas elliott. Ahmadi, shima, upgrading of fast pyrolysis oil via hdo using nanostructured catalysts 2014. Fast pyrolysis liquid is a potential source of revenues for companies who have biomass residues at their disposal.
Exploratory studies on fast pyrolysis oil upgrading. The bio oil yield and organic phase yields obtained from catalytic fast pyrolysis of pm were found to be higher than those obtained from pyrolysis runs with lignocellulosic biomass in the same apparatus in the past stefanidis et al. Fast pyrolysis bio oils are supposed to replace fuel oils in many stationary applications including boilers and furnaces. Fast pyrolysis bio oil process intensive mixing of biomass particles and hot sand in absence of air in the reactor char and sand are recycled to a combustor where the char is burned to reheat the sand vapours leaving the reactor are rapidly cooled in the condenser yielding the pyrolysis oil and some gases. Development of bio fuel industry in the southern region from the bio oil produced from the fast pyrolysis of southern pine requires various upgrading processes. The gases and the surplus heat from the combustor can be used to. The complexity of biomass pyrolysis was simplified using analytical pyrolysis gas chromatographymass spectrometer pygcms for online monitoring of thermal and catalytic ex situ upgrading vapors from several biomass resources, heavy organic fraction of bio oil, levoglucosan and model compounds derived from cellulose pyrolysis. Biooil production from biomass fast pyrolysis and its. The required material and energy inputs involved in the unit processes of lca are taken from aspen plus simulation models established according to a demonstration plant. Pyrolysis methods differ in their residence time, temperature, and heating rate, which in turn. Study on the aging mechanism of pyrolysis biooil aiche. Life cycle assessment of the production of hydrogen and.
Although commercial or demonstration scale fast pyrolysis units can readily produce this oil, this industry has not grown to significant commercial impact due to the lack of bio oil market pull. Fast pyrolysis is a nonequilibrium process and bio oil properties are a function of temperature, pressure, residence time, reactor configuration and quench method. Typically, liquid yields of 6075 wt%, char yields of 1525 wt%, and noncondensable gas yields of 1015 wt. Upgrading biomass pyrolysis biooil to renewable fuels tranlive. Pyrolysis biooil upgrading to renewable fuels 1 executive summary this study aims to upgrade pyrolysis oil into transportation fuels by catalytic hydrodeoxygenation hdo. Fast pyrolysis biooils from wood and agricultural residues. The oil typically contains between 10 and 30% water, depending on the moisture of the biomass. The technology developed under this project can be scaled up and commercialized in the near future. Biooil gasification biooil and char slurried together to recover 90% of the original biomass energy slurry transported to central processing site where it is gasified in an entrained flow gasifier to syngas syngas is catalytic processed into green diesel ft liquids pyrolyzer biooil recovery slurry preparation. Biomass particles at room temperature and hot sand particles are introduced near the bottom of the cone, where the solids are mixed and transported upwards by the rotating action of the cone. Upgrading of biooil into highvalue hydrocarbons via. Fast pyrolysis of biomass for biooil production youtube. We evaluate the economic feasibility of fast pyrolysis and upgrading facilities 11 employing either of two depolymerization pathways. Biooil was produced via the fast pyrolysis of pine at 500.
Technoeconomic analysis of fast pyrolysis and upgrading. Bio oils and transportation fuels by fast pyrolysis several years ago vtt identified that all biofuels are, and for the near future will be, more expensive than their fossil counterparts. The fast pyrolysis of biomass is already being commercialized, while the upgrading via bio oil hydrotreating to transportation fuels has only been demonstrated in the laboratory and on a small engineering development scale. Upgrading of fast pyrolysis oils produced from swtichgrass was carried out using 5 wt % ru and 5 wt % rh on a carbon support as catalysts slurried in a polyethylene glycol solvent in a 300 ml parr batch reactor in the presence of hydrogen. It is typically dark brown or closer to red or dark green depending on the feedstock, very viscous, and smells like a campfire crossed with barbecue sauce mohan et al. Pyrolysis oil, sometimes also known as biocrude or biooil, is a synthetic fuel under investigation as substitute for petroleum.
Pyrolytic oil or bio oil is a kind of tar and normally contains levels of oxygen too high to be considered a hydrocarbon. Bio oil production from biomass fast pyrolysis and its upgrading ronghou liu full professor with tenure, director,phd, biomass energy engineering research centre school of agriculture and biology shanghai jiao. The ideal conditions for fast pyrolysis involve rapid heating rates 400. The primary driver for the economics of liquid hydrocarbon fuel production. The multiscale challenges of biomass fast pyrolysis and. Review of fast pyrolysis of biomass and product upgrading biomass bioenergy. The woody biomass available in the pacific northwest can theoretically produce millions of barrels of pyrolysis biooils per year. Conversion of solid biomass by fast pyrolysis to a more usable form of energy in liquid form which is known as bio oil conversion of this primary liquid product by. Fast pyrolysis bio oil upgrading including gasification product refining offsites including power and heat provision gasification of biomass or bio oil oxygen for gasification gas cleaning for quality gas conditioning for composition potential for ccs synthesis of biofuels hc or oh conversion of alcohols to hc. Catalysts with high activity and selectivity are thereby highly desired in the upgrading process. Coprocessing higher fpbo shares to get more bio c in the products can be.
F per second and temperatures usually in excess of 1,000. Fast pyrolysis biooil applications the presentation herein is intended for presentation purposes and contains confidential information. Mar 31, 2015 fast pyrolysis of biomass for biooil production. The digests 2017 multislide guide to fast pyrolysis and biooil upgrading august 7, 2017 jim lane within the chemcatbio set of core catalysis projects lies fast pyrolysis and upgrading, which has as its goal to develop cost competitive biofuels through catalytic stabilization and deoxygenation of fast pyrolysis biooil. Tea guided development of processes and catalysts for hydrocarbon fuel production from bio oil mypp target. Standards for fast pyrolysis biooil centc 19wg 41 is currently developing standards for fast pyrolysis oils in response to ec mandate m525 20. Analyze process economics of biomass and biofuel processes such as fast pyrolysis of wood, bio oil upgrading, gasification of wood, biodiesel, ethanol fermentation and syngas fermentation. Technoeconomic analysis of biomass fast pyrolysis to.
Fast pyrolysis bio oil in fcc units is a lowcapex option that is proven at demo scale as a viable way to meet renewable fuel requirements, with little to no impact on refinery operations when coprocessing 5 wt% or less. After 1 hour ultrasonication, the water soluble phase separated as the top layer while water insoluble organic phase was the bottom layer. Fast pyrolysis and biooil upgrading build a gasifier. Utilisation of poultry industry wastes for liquid biofuel. Upgrading of biomass fast pyrolysis oil biooil presentation for. Kit ikft thermochemical conversion of biomass fast. Developments in fast pyrolysis may be traced back to a development program by.
Fast pyrolysis bio oil generally has undesired properties such as low heating value, high water content, instability and high level of corrosion as compared to diesel fuel 27, 35. A reactive distillation process for upgrading biooil to. Coprocessing crude fast pyrolysis bio oil in fcc units is a lowcapex option that is proven at demo scale as a viable way to meet renewable fuel requirements, with little to no impact on refinery operations when coprocessing 5 wt% or less. Characterization of hydroprocessed fast pyrolysis oil fractions, mariefel v. It offers the advantages of a liquid product, bio oil that can be readily stored and transported. Zacher, catalytic hydroprocessing of fast pyrolysis biooil to hydrocarbon fuels, oral presentation at abrn. Most of the bio oil upgrading techniques require high amounts of hydrogen, expensive heterogeneous catalysts and capital intensive infrastructure. Partial deoxygenation of biooil by catalytic fast pyrolysis with subsequent.
Life cycle assessment of polyol fuel from corn stover via. It is the most common of the methods, both in research and in practical use. Bio oil pyrolysis liquid bio oil from flash pyrolysis is a low viscosity, darkbrown fluid with up to 15 to 20% water. Fast pyrolysis of biomass is one of the most recent renewable energy processes to have been introduced. Nickel ni and ruthenium ru supported on silica and. Esterification and azeotropic water removal can improve all of these properties. Pyrolysis biooils biodegrade aerobically at a substantially higher rate than hydrocarbon fuels like diesel oil. At the end of the second stage, the oxygen content in the bio oil is. Three standards will be developed for replacement of heavy fuel oil, light fuel oil and for use of bio oils in stationary combusiton engines. Brown iowa state university and jennifer holmgren university of pennsylvania on the decomposition of wood by pyrolysis. However, these bio oils are completely different from petroleum fuels and.
This presentation was a team work of 4 member presented to the faculties of the university of manchester. The purpose of this study is to evaluate the fossil energy consumption and the greenhouse gas ghg emissions of polyol fuel produced via corn stover fast pyrolysis and bio oil upgrading based on life cycle assessment lca. Increasing the viscosity of bio oil during storage is a major problem that can be controlled by the. Among these processes, pyrolysis has the advantages of operating at atmospheric pressure and moderate temperatures 400. Fast pyrolysis of biomass is one of the most anticipated renewable energy technologies since it has a huge potential to become the efficient, environmentally sustainable, and cost effective technology for energy. For instance, yields of up to 75 wt% 6 of pyrolysis oil also known as pyrolysis liquid and bio oil can be achieved. It is obtained by heating dried biomass without oxygen in a reactor at a temperature of about 500 c with subsequent cooling.
Bio oil can be deoxygenated by two theoretical routes. Review of fast pyrolysis of biomass and product upgrading. Brown iowa state university and jennifer holmgren uop. The pyrogas chromatographymass spectroscopy gcms equipment is useful for the rapid and accurate evaluation of different catalysts for fast pyrolysis applications, and it was used here to evaluate the performances of the catalysts bentonite and zsm5 zeolite for upgrading pyrolysis oil produced from e. To produce transportation biofuels via this thermochemical process, fast pyrolysis is followed by bio oil upgrading. Its commercialization, however, poses a multiscale ch. This has become increasingly obvious lately as technologies are moving towards demonstration. Incoming biomass maximum size of pyrolysis biomass conversion to pyrolysis products 480c and 1 atm 2. This technoeconomic study examines fast pyrolysis of corn stover to bio oil with subsequent upgrading of the bio oil to naphtha and diesel range fuels. Biooil production pyrolysis pyrolysis biomass free 30. Pdf fast pyrolysis and biooil upgrading researchgate. Multiple reaction pathways for pyrolysis of cellulose cellulose fast. Decouple biomass resource from location and scale of application works with a variety of lignocellulosic biomass feedstocks produces a homogeneous liquid, a sustainable alternative to fossil fuels fast pyrolysis bio oil is easier to store and transport than solid biomass due to.
The result is biooil, a potentially useful product. Also, these upgrading methods are not effective in producing the fuel in terms of early. Btgs fast pyrolysis technology was originally based on the rotating cone reactor rcr. Technoeconomic performance analysis of biofuel production and miniature electric power generation from biomass fast pyrolysis and bio oil upgrading. Pdf estimation of the production cost of fast pyrolysis biooil.
Pdf upgrading of pyrolysis biooil to fuel over supported. Fast pyrolysis process produces liquid bio oil as a main product, along with solid char and combustible gas. Greater awareness of the potential for fast pyrolysis and biooil to offer more versatile processes routes to a wider range of products and contribute to biorefinery concept development. Pyrolysis liquid biooil from flash pyrolysis is a low viscosity, darkbrown. Fast pyrolysis and ultra fast flash pyrolysis maximize the gases and oil produced. Pyrolysis biooil upgrading to renewable fuels tranlive. Partial polar oxygenate composition of bio oil used in this study six common types of elastomers and grades were evaluated in an offhighway diesel baseline and a mixedoak feedstock bio oil derived via fast pyrolysis sans aqueous phase. Lignocellulosic biomass is converted into bio oil through fast pyrolysis, which is then upgraded to synthetic fuels in a catalytic hydrotreating process.
Upgrading of pyrolysis bio oils to biofuels has viable options for nearterm commercial development for use in petroleum refineries. Production of gasoline and diesel from biomass via fast. Pyrolysis oils can be easily fractionated j o u r n a l p r e p r o o f by. Pyrolysis oil, sometimes also known as biocrude or bio oil, is a synthetic fuel under investigation as substitute for petroleum. Commercial production and applications gerhard muggen, managing director, btgbtl. Pyrolysis oil from biomass pyrolysis oil also bio oil or bio crude oil a dark brown liquid is obtained having typical properties. Other options for pyrolytic processes and upgrading steps exist, but they were not evaluated in this study. The goal of this paper is the evaluation of fast two. Bio oil is a renewable liquid fuel and can also be used for production of chemicals.
Transportation fuels from biomass via fast pyrolysis and. This design case investigates production of fast pyrolysis oil from biomass and the upgrading of that bio oil as a means for generating infrastructureready renewable gasoline and diesel fuels. Fast pyrolysis aims at maximizing the yield of liquid bio oil. Biooil does not appear to be a significant environmental hazard even in raw form, thereby providing a margin of safety in the event of spills. Different alternatives exist as subsequent processing steps. Brown and holmgren 2008 used fast pyrolysis at temperatures between 400 and 500 c, with residence times of 0. Biooil production pyrolysis free download as powerpoint presentation. In this study, the bio oil from the biomass fast pyrolysis is upgraded via hdo which consists of two stages. Computational fluid dynamic cfd coupled with kinetics and reaction mechanisms may enable.
Fast pyrolysis is a rapid thermal decomposition of carbonaceous materials in the absence of oxygen in moderate to high heating rates. Property typical value moisture content 1530% ph 1. Pdf fuel oil quality and combustion of fast pyrolysis. Biooil stabilization by hydrogenation over reduced metal. Exergy analysis of synthetic biofuel production via fast. Removal of entrained solid particles from vapor stream 90% particle removal. Upgrading of intermediate biooil produced by catalytic pyrolysis. Fast pyrolysis biooil pyrolysis liquid from plant residues is one. Feb 08, 2014 biomass fast pyrolysis is a thermochemical process that converts feedstock into gaseous, solid, and liquid products through the heating of biomass in the absence of oxygen.
Pyrolysis bio oil upgrading to renewable fuels 1 executive summary this study aims to upgrade pyrolysis oil into transportation fuels by catalytic hydrodeoxygenation hdo. Upgrading of fast pyrolysis oil via hdo using nanostructured. Previous years assessments may be found in jones et al 2011, 2012, 20b. The result is bio oil, a potentially useful product. Recent development of biomass fast pyrolysis technology and. Fast pyrolysis bio oil pyrolysis liquid from plant residues is one alternative to replace fossil fuels and feedstocks.
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